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矽氧樹脂

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矽氧樹脂亦稱為矽酮,(polymerized siloxanespolysiloxanes)是一個介於有機與無機的聚合物,其化學式為[R2SiO]n,其R= 甲基乙基苯基。 这些材料由无机硅氧键骨架(...-Si-O-Si-O-Si-O-...)和以共价键和硅原子结合的支链有机基团组成。 有些情况下,有机支链可将两个或以上的无机硅氧键骨架连接起来。通过控制骨架的长度,有机基团的种类和骨架的交联,可得到具有不同性质和组成的硅氧树脂。其一致性可变,可从液体到凝胶,橡胶和硬塑料。最常见的种类为线性的polydimethylsiloxane或PDMS(一种硅油)。The second largest group of silicone materials is based on silicone resins, which are formed by branched and cage-like oligosiloxanes.

目录

[编辑] 性质

Some of the most useful properties of silicone include:

  1. 热稳定性 (在–100 to 250°C间能保持稳定性质)
  2. 尽管没有亲脂性,硅氧树脂具有拒水性,可用作水密封。
  3. excellent resistance to oxygen, ozone and sunlight
  4. Flexibility
  5. 良好的电绝缘性
  6. Anti-adhesive
  7. 低化学活性
  8. 低毒性
  9. High gas permeability: at room temperature (25°C) the permeability of silicone rubber for gases like oxygen is approximately 400 times that of butyl rubber, making silicone useful for medical applications (though preculding it from applications where gas tight seals are necessary).

[编辑] 应用

[编辑] 化学术语

在英语中,硅氧树脂(Silicone)经常与(Silicon)混淆。尽管硅氧树脂含有硅原子,但其并不只由硅原子组成。硅氧树脂具有和单质硅完全不同的物理性质

硅氧树脂(Silicone)的英文名称由(Ketone)衍生而来。二甲基硅酮(Dimethylsilicone)具有与丙酮(Acetone)相似的分子式,从而被错误的推断两者具有相似的结构。类似的术语还有硅烷(Silane),名称由甲烷(methane)衍生而来。真正具有硅氧双键的"硅酮"并不存在。聚硅醚(Polysiloxane)由于其早期的错误推断仍被称为硅酮(Silicone)。

[编辑] 使用

[编辑] Sealants in building construction and maintenance

One-part silicone sealants are in common use to seal gaps, joints and crevices in buildings. Silicones are abundantly available for this purpose, in professional, as well as retail grades. One-part silicones cure by absorbing atmospheric moisture, which helps in the professional installation. To make a very smooth silicone seal, apart from masking the edges with tape, if practical, professional caulkers often wet wooden spoons and assorted, hand-crafted wooden tools, which they soak in water with diluted dishsoap. The silicone will not stick to wet, soapy wood, which makes this ideal for creating a perfectly smooth surface. Do-it-yourselfers typically use a moistened finger to trace neat beads into silicone caulking.

Similar methods work for urethane caulking, against which silicones compete quite heavily. White silicones frequently turn slightly yellow over time.

The strength and reliability of silicone rubber is widely acknowledged in the construction industry. Automotive body manufacturing plants and paint shops must avoid the presence of all silicones, as a mere hint of its presence in any form can cause severe failures in automotive paints. Vendors and contractors in such plants are often requested to verify in writing that they will not bring any silicones into the plant.

In the plumbing and automotive fields, silicone grease is often used as a lubricant. Automotive spark plug wires are often insulated by multiple layers of silicone. Such construction prevents spark from jumping to an adjacent wire, causing a misfire. It also minimizes RFI, which can interfere with an engine management computer. In plumbing, the grease is typically applied to O-rings in faucets and valves. In the automotive field, silicone grease is typically used as a lubricant for brake components since it is stable at high temperatures, is not water-soluble, and is far less likely than other lubricants to foul brake pads.

[编辑] Cooking applications

Silicone is also impregnated into parchment paper and used as a non-stick material for applications such as baking and steaming. The silicone also makes the paper heat- and grease-resistant. This allows the paper to line cookie sheets and act as a replacement for greasing, thereby speeding mass production of baked goods. It is also commonly used in pouch cooking, where ingredients are sealed into a container made of parchment paper and allowed to steam.

Silicone rubber is also used to make utensils (notably spatulas) and bakeware.

[编辑] Electronic components

Electronic components are sometimes protected from environmental influence by enclosing them in silicone. This increases the stability against mechanical shock, radiation, vibration and especially the electrical insulation. Silicones are selected over polyurethane or epoxy encapsulation when a wide operating temperature range is required (-150 to 600 F). Silicones also have the advantage of little exothermic heat rise during cure, low toxicity, good electrical properties and high purity. Therefore it is used when durability and high performance are demanded of components under hard conditions, as in space (satellite technology).Silicones, however are relatively expensive and can be attacked by solvents. (See Resin casting for how silicones can be dispensed in circuit board production).

[编辑] Menstrual cups

A Menstrual cup is a type of cup or barrier worn inside the vagina during menstruation to collect menstrual fluid. Menstrual cups are often made of silicone for its durability and reusability.

[编辑] Silicone breast implants

Controversy developed in the 1980s and 1990s around claims that the silicone gel in breast implants was responsible for a number of systemic health problems, including autoimmune diseases and cancer. Multiple lawsuits claiming injury from implants resulted in the 1998 bankruptcy of Dow Corning and a moratorium on the use of silicone implants for breast augmentation in the US and Canada pending study. However, multiple studies and expert review panels performed worldwide since then have consistently concluded that women with silicone breast implants are no more likely to develop systemic illness than women without breast implants. In 2006 both Health Canada and the US FDA adopted positions similar to other countries in permitting the use of silicone implants for cosmetic breast augmentation in their respective countries.

[编辑] Firestops

Silicone foams have been used in North American as well as the Israeli Dimona nuclear reactor buildings in an attempt to firestop openings within fire-resistance rated wall and floor assemblies to prevent the spread of flames and smoke from one room to another. (The Israelis wisely switched to the somewhat more expensive yet much safer "elastomer" version of this product, which avoids most safety concerns associated with the foamed version.) Silicone foam firestops have been the subject of serious controversy and press attention due to lack of proper bounding and smoke development due to the pyrolysis of combustible components within the foam, hydrogen gas escape, shrinkage and cracking. These problems have been exposed by whistleblower Gerald W. Brown and have led to a large number or reportable events among licensees (operators of nuclear power plants) of the Nuclear Regulatory Commission (NRC). When properly installed, silicone foam firestops can be fabricated for building code compliance. Advantages include flexibility and high dielectric strength. Disadvantages include poor bounding, combustibility (hard to extinguish) and significant smoke development.

[编辑] 参见

[编辑] 参考材料

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